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The Effect of Temperature and Catalysts on the Rate Constant.

The value of the rate constant depends on the orientation factor, activation energy and temperature. The rate constant is given by
k = A e -Ea/RT
Ea is the activation energy, R is the gas constant and T is the temperature in Kelvin. This is known as the Arrhenius Equation. Every straight line can be written in the form y = mx + cThe Arrhenius equation gives an exponential curve. But rearranges in the form of a straight line if you use the natural logarithms.Plot ln k against (1/T)
y = mx + c
ln k = -Ea/R1/T + ln A

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Specification: OCR Chemistry A (H432), A-level, 5.1.1 How fast?. Topic: Rate of Reaction.

Key terms in this lesson

activation energy
The minimum energy required for a collision between particles to result in a reaction.
rate constant
The constant of proportionality, k, in the rate equation. Its value depends on temperature.

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