Plane-Polarised Light
Ordinary light is made of electromagnetic waves that vibrate in all planes at right angles to the direction the light travels. When light passes through a polarising filter, only the waves vibrating in one plane get through. This is plane-polarised light.
When plane-polarised light passes through a solution of a single optical isomer, the plane of polarisation is rotated. Optical activity is the ability of a single optical isomer to rotate the plane of polarisation of plane-polarised light, and such a substance is described as optically active.
The two enantiomers of a compound rotate the plane by the same angle but in opposite directions: one clockwise and the other anticlockwise. This is the simplest physical way to tell a pair of enantiomers apart.
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More in Chirality
- Chirality
- Optical Isomers
- Racemic Mixtures
- Racemates from Nucleophilic Addition
- Identifying Chiral Centres
All 6 lessons in Chirality · All Edexcel A-level Chemistry topics