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Biodiesel

AQA A-level ChemistryCarboxylic Acids and DerivativesLesson 11 of 16

Biodiesel is a mixture of methyl esters of long-chain carboxylic acids. It is used as a fuel in diesel engines, either on its own or blended with diesel from crude oil.

It is made by reacting vegetable oils (triglycerides) with methanol in the presence of a catalyst, typically a strong alkali such as sodium or potassium hydroxide. The methanol swaps places with the glycerol in each ester group, so the three fatty acid chains leave as three separate methyl esters, and glycerol is released.

triglyceride + 3CH3OH → 3RCOOCH3 + CH2(OH)CH(OH)CH2OH

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Key terms in this lesson

triglyceride
An ester formed from one molecule of glycerol and three fatty acid molecules, found in vegetable oils and animal fats.

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