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Reduction with NaBH4

AQA A-level ChemistryAldehydes and KetonesLesson 6 of 9

Aldehydes and ketones can be reduced to alcohols using sodium tetrahydridoborate(III), NaBH4, in aqueous solution. NaBH4 acts as a source of the hydride ion, H−.

In equations the reducing agent is written as [H]. Two [H] are added across the C=O bond:

• Aldehydes are reduced to primary alcohols:

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