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Oxidation of Aldehydes

AQA A-level ChemistryAldehydes and KetonesLesson 3 of 9

Aldehydes are easily oxidised to carboxylic acids. The usual oxidising agent is acidified potassium dichromate(VI), K2Cr2O7 with dilute sulfuric acid, and the mixture is heated under reflux so that oxidation is complete.

In equations the oxidising agent is written as [O]:

RCHO + [O] → RCOOH
CH3CHO + [O] → CH3COOH

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