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Reaction with Hydrogen Cyanide

OCR A-level Organic ChemistryCarbonyl CompoundsLesson 4 of 12

Aldehydes and Ketones react with HCN to give hydroxynitriles. HCN is not used as it is an extremely poisonous gas. Instead KCN or sodium cyanide is acidified with a little sulfuric acid. The solution contains free cyanide ions and some hydrogen cyanide (HCN) from the reaction between the KCN and acid.

Diagram

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Key terms in this lesson

nucleophilic addition
A reaction mechanism in which a nucleophile donates a lone pair of electrons to the electron-deficient carbon atom of a pi bond, without any group being displaced.
nucleophile
An atom or group of atoms that can donate a pair of electrons to form a new covalent bond.

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