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Free Radical Substitution

OCR A-level Organic ChemistryAlkanesLesson 8 of 8

The halogenation of alkanes takes place by a mechanism called free radical substitution and can be considered to take place in three steps:

  • initiation
  • propagation
  • termination
Diagram

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Key terms in this lesson

free radical
A species with an unpaired electron.
homolytic fission
The breaking of a covalent bond in which each bonding atom takes one electron from the bonded pair, forming two free radicals.

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