Free Radical Substitution
The halogenation of alkanes takes place by a mechanism called free radical substitution and can be considered to take place in three steps:
- initiation
- propagation
- termination

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Key terms in this lesson
- free radical
- A species with an unpaired electron.
- homolytic fission
- The breaking of a covalent bond in which each bonding atom takes one electron from the bonded pair, forming two free radicals.
More in Alkanes
- Crude Oil
- Cracking and Reforming
- Complete Combustion
- Incomplete Combustion
- Oxides of Sulfur and Nitrogen
- Catalytic Converters
- Alternative Fuels
All 8 lessons in Alkanes · All OCR A-level Organic Chemistry topics