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Dehydration of Alcohols

OCR A-level Organic ChemistryAlcoholsLesson 6 of 7

On heating an alcohol with concentrated phosphoric acid H3PO4, an elimination reaction occurs. A molecule of water is eliminated and an alkene is formed. This reaction is also known as dehydration.

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Key terms in this lesson

elimination
A reaction in which atoms or a small molecule are removed from a molecule, often forming a double bond.
position isomerism
Structural isomerism in which compounds have the same molecular formula but the functional group is in a different position.
E-Z isomerism
A system for naming geometric isomers, in which the two isomers are distinguished by the priority (atomic number) of the groups attached to each carbon of the double bond.

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