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Halogen Disproportionation Reactions

OCR AS-level ChemistryReactivity TrendsLesson 12 of 16

Disproportionation is a redox reaction in which the same element is both oxidised and reduced. Two examples are the reaction of chlorine with water and the reaction of chlorine and cold, dilute aqueous sodium hydroxide.
Cl2(aq) + H2(l) → HClO(aq) + HCl(aq)

The oxidation state of chlorine is +1 in HClO and -1 in HCl.

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Key terms in this lesson

Acid
A proton donor; a substance that releases hydrogen ions when dissolved in water.
Oxidation
The addition of oxygen, the removal of hydrogen, the loss of electrons, or an increase in oxidation number.
Oxidation number
A number that represents the number of electrons involved in an atom's bonding to another element.

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