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Effect of Change in Pressure

Edexcel AS-level ChemistryReversible Reactions and Dynamic EquilibriumLesson 4 of 18

A change in pressure only affects the position of an equilibrium that involves gases, and only when there are different numbers of gas molecules on each side of the equation.

By Le Chatelier's principle:

• Increasing the pressure shifts the equilibrium towards the side with fewer gas molecules, which reduces the pressure.
• Decreasing the pressure shifts the equilibrium towards the side with more gas molecules.

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Key terms in this lesson

le chatelier's principle
If a system at equilibrium is subjected to a change in conditions, the position of equilibrium shifts to oppose that change.
equilibrium constant
A value, Kc, expressing the ratio of product to reactant concentrations at equilibrium for a reaction at a given temperature.

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