When group 2 carbonates are heated they decompose into the oxides and carbon dioxide with increasing difficulty down the group.The smaller the positive ion is, the higher the charge density, and the greater the polarising effect it will have on the carbonate ion.

Thermal Stability of Carbonates
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Specification: Edexcel Chemistry (8CH0), AS-level, Topic 4A: The elements of Groups 1 and 2. Topic: Group 2.
Key terms in this lesson
- charge density
- The charge on an ion divided by its size, greater for smaller ions carrying a bigger charge.
More in Group 2
- Reactions of Oxides with Water
- Trends in Solubility of the Hydroxides
- Uses of the Hydroxides
- Reactions of the Oxides and Hydroxides with Acids
- Trend in Solubility of Sulfates
- Thermal Stability of Nitrates
- Flame Tests
- Test for Ammonium Ions
All 16 lessons in Group 2 · All Edexcel AS-level Chemistry topics