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Empirical Formula

Edexcel AS-level ChemistryAmount of Substance and CalculationsLesson 12 of 39

The empirical formula is the simplest whole number ratio of atoms of each element in a compound.

Some substances do not exist as individual molecules. For example sodium chloride is an ionic salt that exists as a giant lattice. The formula NaCl gives the whole number ratio of atoms of sodium and chlorine.

NaCl is also called the formula unit when calculating relative masses.

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Key terms in this lesson

relative atomic mass
The weighted mean mass of one atom of an element compared with 1/12 of the mass of one atom of carbon-12.

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