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The Fingerprint Region

AQA AS-level ChemistryOrganic AnalysisLesson 7 of 9

The fingerprint region of an IR spectrum is the region below 1500 cm−1.

This region contains many overlapping absorptions from the bending and stretching of the molecule as a whole, including C-C and C-O bonds. The pattern is complicated, and it is unique to each compound, like a human fingerprint. Even two compounds with the same functional group, such as propan-1-ol and butan-1-ol, have different fingerprint regions.

The fingerprint region is not usually used to find functional groups, because the individual absorptions are hard to assign. Instead it is used to identify a specific compound.

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