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Precise Relative Molecular Mass

AQA AS-level ChemistryOrganic AnalysisLesson 4 of 9

The precise relative molecular mass of a molecule is the sum of the precise relative isotopic masses of the atoms in its molecular formula, using the most abundant isotope of each element.

Values usually given in questions:
1H = 1.0078, 12C = 12.0000, 14N = 14.0031, 16O = 15.9949

Method
1. Write each possible molecular formula with the same whole-number Mr.
2. Multiply the number of each type of atom by its precise mass and add them up.
3. Choose the formula whose total matches the measured m/z of the molecular ion.

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