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Electron Configuration

Orbitals fill in order of increasing energy.
The order of filling is:
1s 2s 2p 3s 3p 4s 3d 4p 5s 4d 5p
The 4s orbital is filled before the 3d orbital as the 3d orbital has a higher energy than the 4s orbital.
Each orbital can hold up to 2 electrons as long as they have opposite spins.

The opposite spin helps to counteract the repulsion between electrons in the same orbital. Orbitals with the same energy are occupied singly and then paired when there is no unoccupied orbital left.
 1s   2s  2px 2py 2pz
oxygen   ↿⇂↿⇂↿⇂↿ ↿ 

The electron configuration of krypton of atom number 36 is:
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6

The electron configuration of potassium K of atomic number 19 is
[Ar] 4s1

where [Ar] is the electron configuration of argon. first 30 elements:
elementatomic numberelectron configuration
hydrogen11s1
helium21s2
lithium31s2 2s1
beryllium41s2 2s2
boron51s2 2s2 2p1
carbon61s2 2s2 2p2
nitrogen71s2 2s2 2p3
oxygen81s2 2s2 2p4
fluorine91s2 2s2 2p5
neon101s2 2s2 2p6
sodium111s2 2s2 2p6 3s1
magnesium121s2 2s2 2p6 3s2
aluminium131s2 2s2 2p6 3s2 3p1
silicon141s2 2s2 2p6 3s2 3p2
phosphorus151s2 2s2 2p6 3s2 3p3
sulfur161s2 2s2 2p6 3s2 3p4
chlorine171s2 2s2 2p6 3s2 3p5
argon181s2 2s2 2p6 3s2 3p6
potassium191s2 2s2 2p6 3s2 3p6 4s1
calcium201s2 2s2 2p6 3s2 3p6 4s2
scandium211s2 2s2 2p6 3s2 3p6 4s2 3d1
titanium221s2 2s2 2p6 3s2 3p6 4s2 3d2
vanadium231s2 2s2 2p6 3s2 3p6 4s2 3d3
chromium241s2 2s2 2p6 3s2 3p6 4s1 3d5
manganese251s2 2s2 2p6 3s2 3p6 4s2 3d5
iron261s2 2s2 2p6 3s2 3p6 4s2 3d6
cobalt271s2 2s2 2p6 3s2 3p6 4s2 3d7
nickel281s2 2s2 2p6 3s2 3p6 4s2 3d8
copper291s2 2s2 2p6 3s2 3p6 4s1 3d10
zinc301s2 2s2 2p6 3s2 3p6 4s2 3d10

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Specification: AQA Chemistry (7404), AS-level, 3.1.1.3 Electron configuration. Topic: Atomic Structure.

Key terms in this lesson

Atomic number
The number of protons in the nucleus of an atom.
Atomic orbital
A region in space around the nucleus where there is a 95% probability of finding an electron of a given energy.

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