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Electrochemical Cells

OCR A-level ChemistryElectrochemistryLesson 4 of 14

An electrochemical cell can be made by connecting two half cells together. Each half cell has a different potential so one half cell has a greater tendency to accept electrons than the other. As a result, one half cell releases electrons and the other half gains electrons. The difference in electrode potentials between the two cells, the potential difference, is measured with a voltmeter. The circuit is completed with a salt bridge which is a piece of filter paper soaked in aqueous potassium or ammonium nitrate or potassium chloride. The salt bridge is soaked in an ionic compound that does not react with either of the solutions in the half cells.

Diagram

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Key terms in this lesson

half cell
A system consisting of an element in two different oxidation states, in which an equilibrium is set up between the two forms.

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