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Ligand Substitution Reactions

AQA A-level ChemistryTransition MetalsLesson 8 of 21

If concentrated HCl is added to a solution of hexaaquacopper (II) ions the solution turns from blue to yellow. The tetrachlorocuprate (II) complex is more stable than hexaaquacopper (II) ions. There is little enthalpy change because bonds are of similar strength.

Diagram

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Key terms in this lesson

entropy
A measure of the number of ways particles and energy can be arranged in a system, often described as the amount of disorder.

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