The half-life of a reactant is the time taken for the concentration of a reactant to reduce by half. If the order is zero with respect to a reactant, the concentration of the reactant does not affect the rate of reaction. A zero-order reaction has a decreasing half-life. If the order is one with respect to a reactant, the rate of reaction doubles if the concentration of the reactant doubles. The rate is directly proportional to the concentration. A first-order reaction has a constant half-life. If the order is two with respect to a reactant, the rate is proportional to the square of the concentration of the reactant. A second-order reaction has an increasing half-life.
Half-Lives and Reaction Rate Graphs
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Specification: AQA Chemistry (7405), A-level, 3.1.9.2 Determination of rate equation. Topic: Rate of Reaction.
Key terms in this lesson
- acid dissociation constant
- The equilibrium constant, given the symbol Ka, for the dissociation of a weak acid into its ions in aqueous solution.
More in Rate of Reaction
- Experimental Determination of the Rate of Reaction
- The Rate Equation
- The Order of a Reaction
- The Rate Constant k
- Worked Example
- The Rate Determining Step
- Catalysts
- The Effect of Temperature and Catalysts on the Rate Constant.
All 11 lessons in Rate of Reaction · All AQA A-level Chemistry topics