Reactions of Alkenes
The pi bond is weaker than the sigma bond so is broken more readily. The C-C bond has an enthalpy of 347kJmol-1 whilst the C=C bond has an enthalpy of 612 kJmol-1

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Key terms in this lesson
- addition
- A reaction in which a pi bond is broken and atoms or groups are added across it to form a saturated product, with no atoms lost.
- hydrogenation
- The addition of hydrogen across a carbon-carbon double bond, using a nickel catalyst, to form a saturated compound.
- electrophilic addition
- A reaction mechanism in which an electrophile is attracted to and attacks an electron-rich double bond, and a nucleophile then bonds to the resulting carbocation.
- halogenation
- A reaction in which a halogen atom is substituted for a hydroxyl group or a hydrogen atom in a molecule.
More in Alkenes
- Alkenes
- Bonding in Alkenes
- Stereoisomerism in Alkenes
- Hydrogenation
- Reaction with Halogens
- Reaction with Hydrogen Halides
- Reaction with Steam
- Oxidation of Alkenes to Diols
All 11 lessons in Alkenes · All OCR A-level Organic Chemistry topics