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Oxidation of Alkenes to Diols

OCR A-level Organic ChemistryAlkenesLesson 9 of 11

A diol is a compound containing two hydroxyl -OH groups. On oxidising an alkene with acidified potassium permanganate two -OH groups are added across the double bond. The reaction is an addition and an oxidation. Water in the solution provides two hydrogen atoms and one oxygen atom whilst the potassium permanganate provides the other oxygen atom. During the reaction, the potassium permanganate solution turns from purple to colourless.

Diagram

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Key terms in this lesson

addition
A reaction in which a pi bond is broken and atoms or groups are added across it to form a saturated product, with no atoms lost.
oxidation
A reaction in which hydrogen atoms are removed from, or oxygen atoms are added to, an organic molecule.

More in Alkenes

All 11 lessons in Alkenes · All OCR A-level Organic Chemistry topics