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Trends in Ionisation Energy

OCR AS-level ChemistryAtoms, Ions and CompoundsLesson 17 of 17

Ionisation energies increase across a period. This is because the nuclear charge is increasing as there are more protons, but the amount of shielding is the same or similar so the atomic radius decreases across a period.

Shielding refers to the repulsion of the electron to be removed by the electrons in the inner shells.

From group 2 to 3 however, the ionisation energy decreases. This is because elements in group 3 have their outer electron in the p orbital, which is of slightly higher energy than the s orbital outer electrons of group 2 elements. The p orbital electron in group 3 needs less energy to remove it.

Diagram

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Key terms in this lesson

Ionisation
The loss or gain of electrons by an atom or molecule to form a charged ion.
Electron shell
A main energy level occupied by electrons, given a principal quantum number n, with n = 1 closest to and lowest in energy relative to the nucleus.
Atomic orbital
A region in space where there is a high probability (90-95%) of finding an electron.
Group
A vertical column of the periodic table, containing elements with the same number of outer-shell electrons.
Period
A horizontal row of the periodic table, containing elements with the same number of electron shells.

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