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Relative Molecular Mass

The relative molecular mass, Mr, is the weighted mean mass of a molecule compared with one twelfth of the mass of an atom of carbon-12.It is found by adding together the relative atomic masses of all the atoms in the molecular formula. For example, water H2O has Mr = (2 × 1.0) + 16.0 = 18.0, and glucose C6H12O6 has Mr = 180.0.The term is used for substances made of simple molecules. For giant ionic compounds such as sodium chloride, which have no molecules, the term relative formula mass is used instead.Mr has no units because it is a ratio of masses. It can be measured using a mass spectrometer, where the molecular ion peak with the highest m/z value gives the relative molecular mass.

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Specification: OCR Chemistry A (H032), AS-level, 2.1.3 Amount of substance. Topic: Amount of Substance.

Key terms in this lesson

molecular ion
The positive ion, M+, formed in a mass spectrometer when a molecule loses one electron; its mass gives the relative molecular mass.
mass-to-charge ratio
The ratio of the mass of an ion to its charge, given the symbol m/z, used to identify ions in a mass spectrum.

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