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Trend in Reactivity

Reactivity decreases down the group. Because of their high electronegativities they are oxidising agents and are able to gain electrons to form negative ions.Reactivity decreases for the same reason electronegativity decreases:•nuclear charge - the bigger the nuclear charge the higher the electronegativity• the distance between the nucleus and bonding pair of electrons. The shorter the distance the higher the electronegativity•the fewer the energy levels the smaller the shielding effect therefore the higher the electronegativity

Halogens as Oxidising Agents

Fluorine is the most powerful oxidising agent and iodine is the least powerful oxidising agent.By contrast, Iodide ions have the greatest reducing power and fluoride ions have the least reducing power.

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Specification: Edexcel Chemistry (8CH0), AS-level, Topic 4B: The elements of Group 7 (halogens). Topic: Group 7.

Key terms in this lesson

oxidising agent
A substance that accepts electrons from another species, causing it to be oxidised, while it is itself reduced.
electronegativity
The ability of a bonded atom to attract the shared pair of electrons in a covalent bond towards itself.

More in Group 7

All 14 lessons in Group 7 · All Edexcel AS-level Chemistry topics