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Trends in Melting and Boiling Points

Across periods 2 and 3, the melting point increases from group 1 to group 4 (group 14 in the current numbering) then there is a sharp decrease in melting point between group 4 and 5. The melting points of groups 5, 6, 7 and 0 are lower than those in the first four groups.The elements in groups 1 to 4 have giant structures. The elements in groups 5 to 7 have simple molecular structures and group 0 elements exist as single atoms.Giant structures are held together by strong metallic, covalent or ionic bonds and need a lot of energy to break these bonds. Simple molecules have weak intermolecular forces between them. Less energy is needed to overcome these forces so they have much lower melting points.Period 2 Melting Points K:
LiBeBCNOFNe
454156023483823635453.524.5

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Specification: AQA Chemistry (7404), AS-level, 3.2.1.2 Physical properties of Period 3 elements. Topic: Periodicity.

Key terms in this lesson

Group
A vertical column of the periodic table, containing elements with the same number of outer-shell electrons.
Period
A horizontal row of the periodic table, containing elements with the same number of electron shells.

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