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Group 2 and 3

Although there is a general trend in first ionisation energies across a period, and the ionisation energy increases across the period, except from group 2 to group 3.
Boron has a lower ionisation energy than beryllium because outer electron of beryllium is in the 2s sub-shell whilst the outer electron of Boron is in the 2p sub-shell.
The 2p electron is easier to remove than the 2s electron because the 2p sub-shell has a higher energy than the 2s sub-shell.
Period 2 ionisation energies kJmol-1:
LiBeBCNOFNe
520.2899.5800.61086.51402.31313.91681.02080.7

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Specification: AQA Chemistry (7404), AS-level, 3.2.1.2 Physical properties of Period 3 elements. Topic: Periodicity.

Key terms in this lesson

Sub-shell
A subdivision of a main energy level (s, p, d or f) containing orbitals of similar energy.
First ionisation energy
The enthalpy change when each atom in one mole of gaseous atoms loses one electron to form one mole of gaseous 1+ ions.
Group
A vertical column of the periodic table, containing elements with the same number of outer-shell electrons.
Period
A horizontal row of the periodic table, containing elements with the same number of electron shells.

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