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Trends in Oxidising Ability

The halogen acts as the oxidising agents.The most common type of reactions are redox reactions.2Li + Cl2 → 2LiClThe most vigorous reactions are between Caesium (low first I.E.) and Fluorine (very small, only needs to gain one electron). The least vigorous reaction is between beryllium and iodine.The salts formed are white ionic salts. All the reactions involve electron transfer so are redox reactions.
Each halogen has seven outer shell electrons. Each halogen atom is reduced, gaining one electron to form a 1- halide ion with the electron configuration of the nearest noble gas.Cl2 + 2e- → 2Cl-The halogen takes electrons from the other species, which is oxidised, so the halogens are oxidising agents.The reactivity of the halogen decreases down the group as the tendency to gain electrons decreases.

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Specification: AQA Chemistry (7404), AS-level, 3.2.3.1 Trends in properties. Topic: Group 7.

Key terms in this lesson

Electron configuration
The arrangement of electrons in an atom's shells and sub-shells, written using numbers and letters such as 1s2 2s2.
Oxidising agent
A species that accepts electrons from another species, causing that species to be oxidised.
Group
A vertical column of the periodic table, containing elements with the same number of outer-shell electrons.

More in Group 7

All 20 lessons in Group 7 · All AQA AS-level Chemistry topics