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Electronegativity

Electronegativity is the ability of a bonded atom to attract the pair of electrons in a covalent bond.The Pauling scale used is from 0 - 4. Electronegativity decreases down the group.Because of their high electronegativities they are oxidising agents and are able to gain electrons to form negative ions. Electronegativity decreases because:•nuclear charge - the bigger the nuclear charge the higher the electronegativity• the distance between the nucleus and bonding pair of electrons. The shorter the distance the higher the electronegativity.•the fewer the energy levels the smaller the shielding effect therefore the higher the electronegativity
elementelectronegativity
fluorine4.0
chlorine3.0
bromine2.8
iodine2.5
astatine2.2

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Specification: AQA Chemistry (7404), AS-level, 3.2.3.1 Trends in properties. Topic: Group 7.

Key terms in this lesson

Shielding
The repulsion of outer electrons by electrons in inner shells, which reduces the net attraction of the nucleus for the outer electrons.
Covalent bond
A strong electrostatic attraction between a shared pair of electrons and the nuclei of the bonded atoms.
Oxidising agent
A species that accepts electrons from another species, causing that species to be oxidised.
Group
A vertical column of the periodic table, containing elements with the same number of outer-shell electrons.

More in Group 7

All 20 lessons in Group 7 · All AQA AS-level Chemistry topics