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Empirical Formula

AQA AS-level ChemistryAmount of SubstanceLesson 19 of 33

The empirical formula is the simplest whole number ratio of atoms of each element in a compound.

Some substances do not exist as individual molecules. For example sodium chloride is an ionic salt that exists as a giant lattice. The formula NaCl gives the whole number ratio of atoms of sodium and chlorine.

NaCl is also called the formula unit when calculating relative masses.

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Key terms in this lesson

Relative atomic mass
The weighted mean mass of an atom of an element compared to 1/12th the mass of a carbon-12 atom.
Relative molecular mass
The weighted mean mass of a molecule compared to 1/12th the mass of a carbon-12 atom.
Mole
The amount of substance that contains as many particles as there are atoms in exactly 12g of carbon-12.
Molecular formula
The actual number of atoms of each element in a molecule.

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