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Enthalpy Change of Solution

OCR A-level ChemistryLattice EnthalpyLesson 10 of 10

When a solid dissolves the ionic lattice breaks down or dissociates (endothermic) and the ions become hydrated (exothermic). The resulting enthalpy change is called the enthalpy of solution. The energy needed to break down the lattice is the lattice dissociation enthalpy. This has the same magnitude as the lattice enthalpy but has the opposite sign.

Diagram

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Key terms in this lesson

enthalpy change of hydration
The enthalpy change when one mole of gaseous ions dissolves in water to form one mole of aqueous ions, under standard conditions.
Born-Haber cycle
An enthalpy cycle, based on Hess's law, used to calculate lattice enthalpy or another enthalpy change that cannot be measured directly.

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