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Enthalpy Change of Solution

When a solid dissolves the ionic lattice breaks down or dissociates (endothermic) and the ions become hydrated (exothermic). The resulting enthalpy change is called the enthalpy of solution. The energy needed to break down the lattice is the lattice dissociation enthalpy. This has the same magnitude as the lattice enthalpy but has the opposite sign.The next stage involves the hydration of the gaseous ions. Energy is released when the ions form bonds with water molecules. This energy is the enthalpy change of hydration. A Born-Haber Cycle can be used to show or calculate the energy changes. The gaseous ions are placed at the top of the cycle and there are two routes that connect the gaseous ions to the ionic solid.

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Specification: OCR Chemistry A (H432), A-level, 5.2.1 Lattice enthalpy. Topic: Lattice Enthalpy.

Key terms in this lesson

enthalpy change of hydration
The enthalpy change when one mole of gaseous ions dissolves in water to form one mole of aqueous ions, under standard conditions.
Born-Haber cycle
An enthalpy cycle, based on Hess's law, used to calculate lattice enthalpy or another enthalpy change that cannot be measured directly.

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