The standard enthalpy of formation of sodium oxide is -414kJmol-1. The equation is:2Na(s) + ½O2(g) → Na2O(s)The definition states that the -414kJ is the enthalpy for 1 mole of sodium oxide. The definition of the enthalpy of atomisation is for the formation of 1 mole of sodium atoms but we need to atomise 2 Na(s) so the enthalpy change will be 2x +108 kJ mol-1. The definition of the enthalpy of atomisation is for the formation of 1 mole of oxygen atoms. So we can use the standard enthalpy of atomisation which is +249 kJmol-1 as it is. The next step is to ionise the sodium. The equation is:Na(g) → Na+(g) + e-The ionisation energy for sodium is +496 kJ per mole so we double it (we need 2 moles of sodium for each mole of sodium oxide). Mass and charge are conserved for each step. We now have two electron affinities for oxygen. The first is exothermicO(g) + e- → O-(g)The second is endothermic.O-(g) + e- → O2-(g)The cycle is completed with the Lattice (formation) enthalpy2Na+(g) + O2-(g) → Na2O (s)Always include state symbols.
Born-Haber Cycle for Sodium Oxide
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Specification: OCR Chemistry A (H432), A-level, 5.2.1 Lattice enthalpy. Topic: Lattice Enthalpy.
Key terms in this lesson
- standard enthalpy change of formation
- The enthalpy change when one mole of a compound is formed from its constituent elements in their standard states, under standard conditions.
- standard enthalpy change of atomisation
- The enthalpy change when one mole of gaseous atoms is formed from an element in its standard state, under standard conditions.
- first ionisation energy
- The enthalpy change when one electron is removed from each atom in one mole of gaseous atoms, forming one mole of gaseous 1+ ions, under standard conditions.
- first electron affinity
- The enthalpy change when one electron is added to each atom in one mole of gaseous atoms, forming one mole of gaseous 1- ions, under standard conditions.
- lattice enthalpy
- The enthalpy change when one mole of an ionic compound is formed from its constituent gaseous ions, under standard conditions.
More in Lattice Enthalpy
- The Standard Enthalpy Change of Atomisation
- First Ionisation Energy
- First Electron Affinity
- Lattice Enthalpy
- Born-Haber Cycles
- Born-Haber Cycle for Calcium Chloride
- Enthalpy Change of Hydration
- Enthalpy Change of Solution
All 10 lessons in Lattice Enthalpy · All OCR A-level Chemistry topics