On heating an alcohol with concentrated phosphoric acid H3PO4, an elimination reaction occurs. A molecule of water is eliminated and an alkene is formed. This reaction is also known as dehydration.For some alcohols with more than three carbon atoms, there may be more than one possible product due to the positional isomerism of the double bond forming between different carbon atoms, and E-Z isomerism due to the presence of a double bond.The dehydration of butan-2-ol is as follows:CH3CH(OH)CH2CH3 → CH2=CHCH2CH3 + H2OCH3CH(OH)CH2CH3 → CH3CH=CHCH3 + H2O
Dehydration of Alcohols
Read the text
Read the text and highlight anything you think is important. When you go on, the text is hidden and you answer from memory.
Specification: OCR Chemistry A (H432), A-level. Topic: Alcohols.
More in Alcohols
- Alcohols
- Physical Properties
- Classifying Alcohols
- Combustion and use as Fuels
- Oxidation
- Nucleophilic Substitution Reactions
All 7 lessons in Alcohols · All OCR A-level Chemistry topics