Fehling's and Benedict's Solutions
Fehling's solution and Benedict's solution are both blue, alkaline solutions containing copper(II) ions, Cu2+. In Fehling's solution the Cu2+ ions are held in solution as a complex with tartrate ions; in Benedict's solution they are complexed with citrate ions. Both are used to tell aldehydes apart from ketones.
To do the test, add a few drops of the carbonyl compound to the reagent and warm in a hot water bath.
Aldehyde: the blue solution gives a brick-red precipitate of copper(I) oxide, Cu2O.
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More in Carbonyl Compounds
- Naming Carbonyl Compounds
- Physical Properties of Carbonyls
- Oxidation of Aldehydes
- Tollens' Reagent
- Iodoform Reaction
- 2,4-DNPH Test
- Reduction with LiAlH4
- Reaction with HCN
All 11 lessons in Carbonyl Compounds · All Edexcel A-level Chemistry topics