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Fehling's and Benedict's Solutions

Edexcel A-level ChemistryCarbonyl CompoundsLesson 6 of 11

Fehling's solution and Benedict's solution are both blue, alkaline solutions containing copper(II) ions, Cu2+. In Fehling's solution the Cu2+ ions are held in solution as a complex with tartrate ions; in Benedict's solution they are complexed with citrate ions. Both are used to tell aldehydes apart from ketones.

To do the test, add a few drops of the carbonyl compound to the reagent and warm in a hot water bath.

Aldehyde: the blue solution gives a brick-red precipitate of copper(I) oxide, Cu2O.

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