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Reactions of Sodium and Magnesium with Water

AQA A-level ChemistryPeriod 3 Elements and OxidesLesson 2 of 10

Sodium reacts vigorously with cold water. It floats, melts into a ball (the reaction is exothermic and sodium has a low melting point), fizzes as hydrogen is given off and moves around on the surface until it disappears. The solution left is strongly alkaline (pH about 12 to 14).

2Na(s) + 2H2O(l) → 2NaOH(aq) + H2(g)

Magnesium reacts only very slowly with cold water, giving a few bubbles of hydrogen over a long time. Magnesium hydroxide is only slightly soluble, so the solution is only weakly alkaline (pH about 9 to 10).

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