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pH of Period 3 Oxide Solutions

AQA A-level ChemistryPeriod 3 Elements and OxidesLesson 7 of 10

The pH of the solution formed when each Period 3 oxide is added to water:

• Na2O: pH 14 (strongly alkaline)
• MgO: pH about 9 to 10 (weakly alkaline)
• Al2O3 and SiO2: pH 7 (insoluble, so the water is unchanged)
• P4O10: pH about 0 to 1
• SO2: pH about 2 to 3
• SO3: pH about 0 to 1

Why the metal oxides give alkaline solutions. Ionic oxides contain the oxide ion, a strong base, which takes a proton from water:

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Key terms in this lesson

ionic product of water
The equilibrium constant for the ionisation of water, Kw = [H+][OH-], equal to 1.0 x 10-14 mol2 dm-6 at 25 degrees C.

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