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Identifying Functional Groups

OCR A-level Organic ChemistryOrganic SynthesisLesson 6 of 9

In synthesis and analysis you often need to find which functional groups a compound has. OCR expects you to do this using the chemical reactions you have met in the specification: each group gives a characteristic, observable result with a particular reagent.

Key tests:

• alkene (C=C): bromine water, orange to colourless
• haloalkane: silver nitrate in ethanol, warm; precipitate of silver halide
• carbonyl (aldehyde or ketone): 2,4-dinitrophenylhydrazine (2,4-DNP), orange precipitate
• aldehyde: Tollens' reagent, silver mirror (ketones do not react)

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