Reaction with Ammonia
The reaction of halogenoalkanes with ammonia is a nucleophilic substitution. The halogenoalkane is heated with ammonia in a sealed tube to form a primary amine. The first step produces a salt and the second step is the reaction of excess ammonia with the salt.

Sign in free to see the rest of this lesson, the R.E.C.I.P.E. recall steps and the quiz
BrainCake is free. Make an account in seconds and pick up where this page stops.
Key terms in this lesson
- nucleophilic substitution
- A reaction mechanism in which a nucleophile donates a lone pair of electrons to an electron-deficient carbon atom, displacing a leaving group.
More in Halogenolkanes
- Halogenoalkanes
- Reactivity of Halogenoalkanes
- Nucleophilic Substitution - Hydrolysis
- Elimination
- Organohalogen compounds and the Environment
All 6 lessons in Halogenolkanes · All OCR A-level Organic Chemistry topics