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Reaction with Ammonia Solution

OCR A-level ChemistryRedox ReactionsLesson 17 of 21

Ammonia can act as both a ligand and a base. In dilute ammonia solution, ammonia acts as a source of OH- ions and transition metal ions react to form coloured precipitates as hydrolysis reactions occur. When an excess of ammonia is added ligand substitution takes place.

Diagram

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Key terms in this lesson

ligand substitution
A reversible reaction in which one ligand in a complex ion is replaced by another.
octahedral complex
A complex ion with a co-ordination number of six, in which the ligands are arranged symmetrically around the central metal ion.

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