Electrochemical cells are used as a source of electrical energy. They are made of two half cells with different electrode potentials. There are three main types: Non-rechargeable cells, rechargeable cells and fuel cells. With non-rechargeable cells the reactions continue until the reactants are used up. The voltage then drops and the cell gets flat. It is then discarded.AA batteries consist of a zinc anode and cathode made of a carbon rod full of granules of manganese (IV) oxide in a paste of ammonium chloride (electrolyte). Alkaline batteries have sodium hydroxide as the electrolyte. At the anode zinc is oxidised.:Zn(s) + 2OH-(aq) → Zn(OH)2(s) + 2e-At the cathode manganese (IV) oxide is reduced to a manganese (III) compound.:2MnO2(s) + 2H2O(l) + 2e- → 2 MnO(OH)(s) + 2OH-(aq)Mercury batteries are used in watches and pacemakers. They have a zinc anode and a steel cathode and the electrolyte is a paste of mercury(II) oxide in alkali. The reactions in rechargeable cells can be reversed using electrical energy so the cell can be re-used. Examples are Ni-Cd (nickel-cadmium) batteries, lithium-ion batteries and lithium polymer batteries used in laptops.
Electrochemical Cells
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Specification: Edexcel Chemistry (9CH0), A-level, Topic 14: Redox II. Topic: Electrochemistry.
More in Electrochemistry
- Standard Electrode Potential Eθ and the Electrochemical Series
- Calomel Electrode
- Standard Cell Potentials Eθcell Values and Electrochemical Cells
- Non-Standard Conditions
- Cell Diagrams
- Thermodynamic Feasibility of a Reaction and the Extent of a Reaction
- Rechargeable Batteries
- Alkaline Fuel Cells
All 14 lessons in Electrochemistry · All Edexcel A-level Chemistry topics