The total entropy change ΔStotal is the sum of the entropy changes of the system and of the surroundings. When an exothermic change takes place heat energy is transferred to the surroundings causing an increase in disorder to the surroundings. At higher temperatures, the molecules have a greater range of energies so they are more random and more disordered.Since ΔSθsurroundings = -ΔH / T (T is in kelvin) for all exothermic reactions ΔSθsurroundings is positive and for all endothermic reactions ΔSθsurroundings is negative.If the surroundings are hot, the entropy increase is small because the molecules are already in chaotic motion and already have a high entropy.
The Entropy Change of the Surroundings
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Specification: AQA Chemistry (7405), A-level, 3.1.8.2 Gibbs free-energy change, G, and entropy change, S. Topic: Entropy.
Key terms in this lesson
- haber process
- The industrial process for manufacturing ammonia from nitrogen and hydrogen, using an iron catalyst, a compromise temperature and high pressure.